Offline Files Is Trying To Synchronize With Old Server Name
I ran across this problem not too long ago where after upgrading to a new file server, users that had been previously synchronizing their Offline Files were having issues with Offline Files still trying to synchronize with the original / old file server name. The old server was already decommissioned and removed, so the only way I could resolve this was by doing the following steps in order:
-Disabling Offline Files
-Restart the PC
-Delete the C:\Windows\CDC directory
-Delete registry key: HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\NetCache
-Restart the PC
-Enable Offline Files
-Restart the PC


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